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ABSTRACT:
SUBMITTER: Buter J
PROVIDER: S-EPMC3714862 | biostudies-literature | 2013 May
REPOSITORIES: biostudies-literature
Buter Jeffrey J Yeh Edmund A-H EA Budavich Owen W OW Damodaran Krishnan K Minnaard Adriaan J AJ Curran Dennis P DP
The Journal of organic chemistry 20130425 10
(4S,8S,12S,16S,20S)-Pentamethylheptacosan-1-ol has been synthesized and analyzed by resolution-enhanced NMR spectroscopy with the aid of a recent set predicted spectra of all its stereoisomers. The configuration was confirmed, but isomer purity of the sample (~70%) was lower than expected. A truncated analogue, (2S,6S,10S,14S)-2,6,10,14-tetramethylhenicosan-1-ol TBDPS ether, was prepared from a late stage synthetic intermediate. Analysis of its spectra confirmed the configuration and showed that ...[more]