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Polymer-supported siloxane transfer agents for Pd-catalyzed cross-coupling reactions.

ABSTRACT: The design, synthesis, and validation of a ring-opening metathesis polymerization (ROMP) polymer supporting siloxane transfer agents have been achieved that permit efficient palladium-catalyzed cross-coupling reactions. The solubility properties of the polymer facilitate not only product purification but also polymer recycling without significant loss of cross-coupling activity.

SUBMITTER: Nguyen MH

PROVIDER: S-EPMC3771667 | biostudies-literature | 2013 Aug

REPOSITORIES: biostudies-literature

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Polymer-supported siloxane transfer agents for Pd-catalyzed cross-coupling reactions.

Nguyen Minh H MH Smith Amos B AB

Organic letters 20130731 16

The design, synthesis, and validation of a ring-opening metathesis polymerization (ROMP) polymer supporting siloxane transfer agents have been achieved that permit efficient palladium-catalyzed cross-coupling reactions. The solubility properties of the polymer facilitate not only product purification but also polymer recycling without significant loss of cross-coupling activity. ...[more]

PMID: 23901881

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