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Catena-Poly[aqua-bis-(?-3-chloro-benzo-ato-?(2) O:O')zinc].

ABSTRACT: In the polymeric title compound, [Zn(C7H4ClO2)2(H2O)] n , the Zn(II) cation is located on a twofold rotation axis and is coordinated by carboxylate O atoms of four monodentate chloro-benzoate anions and by one water mol-ecule, located on a twofold rotation axis, in a distorted square-pyramidal geometry. In the anion, the carboxyl-ate group is twisted away from the attached benzene ring by 44.16?(11)°. The chloro-benzoate anion bridges Zn(II) cations, forming polymeric chains running along the c-axis direction. O-H?O hydrogen bonds between coordinating water mol-ecules and carboxyl-ate groups link adjacent chains into layers parallel to the bc plane.

SUBMITTER: Bozkurt N

PROVIDER: S-EPMC3772418 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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catena-Poly[aqua-bis-(μ-3-chloro-benzo-ato-κ(2) O:O')zinc].

Bozkurt Nihat N Dilek Nefise N Caylak Delibaş Nagihan N Necefoğlu Hacali H Hökelek Tuncer T

Acta crystallographica. Section E, Structure reports online 20130615 Pt 7

In the polymeric title compound, [Zn(C7H4ClO2)2(H2O)] n , the Zn(II) cation is located on a twofold rotation axis and is coordinated by carboxylate O atoms of four monodentate chloro-benzoate anions and by one water mol-ecule, located on a twofold rotation axis, in a distorted square-pyramidal geometry. In the anion, the carboxyl-ate group is twisted away from the attached benzene ring by 44.16 (11)°. The chloro-benzoate anion bridges Zn(II) cations, forming polymeric chains running along the c- ...[more]

PMID: 24046561

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