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Chlorido[2,2'-[1,2-phenyl-enebis(nitrilo-methanylyl-idyne)]diphenolato-?(4) O,N,N',O']manganese(III) methanol monosolvate.

ABSTRACT: In the title complex, [Mn(C20H14N2O2)Cl]·CH3OH, the central Mn(III) atom displays a distorted square-pyramidal coordination by two N and two O atoms from the tetradentate 2,2'-[1,2-phenyl-enebis(nitrilo-methanylyl-idyne)]diphenolate ligand and one chloride ligand. The Mn(III) atom is 0.525?(4)?Å out of the square basal N2O2 least-squares plane. The complex mol-ecule is hydrogen bonded to the methanol solvent mol-ecule.

SUBMITTER: Lin H

PROVIDER: S-EPMC3772432 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Chlorido[2,2'-[1,2-phenyl-enebis(nitrilo-methanylyl-idyne)]diphenolato-κ(4) O,N,N',O']manganese(III) methanol monosolvate.

Lin Hui H Wang Jian-Gang JG Shi Hua-Tian HT Chen Qun Q Zhang Qian-Feng QF

Acta crystallographica. Section E, Structure reports online 20130619 Pt 7

In the title complex, [Mn(C20H14N2O2)Cl]·CH3OH, the central Mn(III) atom displays a distorted square-pyramidal coordination by two N and two O atoms from the tetradentate 2,2'-[1,2-phenyl-enebis(nitrilo-methanylyl-idyne)]diphenolate ligand and one chloride ligand. The Mn(III) atom is 0.525 (4) Å out of the square basal N2O2 least-squares plane. The complex mol-ecule is hydrogen bonded to the methanol solvent mol-ecule. ...[more]

PMID: 24046575

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