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N-[(3-Ethyl-phen-yl)carbamo-thio-yl]-2,2-di-phenyl-acetamide.

ABSTRACT: In the title mol-ecule, C23H22N2OS, the di-phenyl-acetyl and ethyl-benzene groups adopt a trans-cis conformation, respectively, with respect to the S atom across the (S=)C-N bonds. This conformation is stabilized by an intra-molecular N-H?O hydrogen bond and a weak C-H?S hydrogen bond. The ethyl-substituted benzene ring forms dihedral angles of 87.53?(15) and 73.94?(15)° with the phenyl rings. In the crystal, N-H?O hydrogen bonds link mol-ecules into chains along [100]. A weak C-H?? inter-action is also observed.

SUBMITTER: Yusof MS

PROVIDER: S-EPMC3772456 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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N-[(3-Ethyl-phen-yl)carbamo-thio-yl]-2,2-di-phenyl-acetamide.

Yusof Mohd Sukeri Mohd MS Razali Nur Rafikah NR Arshad Suhana S Rahman Azhar Abdul AA Razak Ibrahim Abdul IA

Acta crystallographica. Section E, Structure reports online 20130608 Pt 7

In the title mol-ecule, C23H22N2OS, the di-phenyl-acetyl and ethyl-benzene groups adopt a trans-cis conformation, respectively, with respect to the S atom across the (S=)C-N bonds. This conformation is stabilized by an intra-molecular N-H⋯O hydrogen bond and a weak C-H⋯S hydrogen bond. The ethyl-substituted benzene ring forms dihedral angles of 87.53 (15) and 73.94 (15)° with the phenyl rings. In the crystal, N-H⋯O hydrogen bonds link mol-ecules into chains along [100]. A weak C-H⋯π inter-action ...[more]

PMID: 24046599

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