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(E)-1-(3-Chloro-phen-yl)-2-(2-oxidonaphthalen-1-yl)diazen-1-ium.

ABSTRACT: The title zwitterion,, C16H11ClN2O, is approximately planar, the dihedral angle between the benzene ring and naphthalene ring system is 1.55?(13)°; an intra-molecular N-H?O hydrogen bond stabilizes the planar conformation. In the crystal, ?-? stacking between the benzene ring and the naphthalene ring system of adjacent mol-ecules links the mol-ecules into supra-molecular chains running along the b axis, the centroid-centroid distance being 3.765?(2)?Å.

SUBMITTER: Benosmane A

PROVIDER: S-EPMC3772459 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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(E)-1-(3-Chloro-phen-yl)-2-(2-oxidonaphthalen-1-yl)diazen-1-ium.

Benosmane Ali A Mili Assia A Bouguerria Hassiba H Bouchoul Abdelkader A

Acta crystallographica. Section E, Structure reports online 20130608 Pt 7

The title zwitterion,, C16H11ClN2O, is approximately planar, the dihedral angle between the benzene ring and naphthalene ring system is 1.55 (13)°; an intra-molecular N-H⋯O hydrogen bond stabilizes the planar conformation. In the crystal, π-π stacking between the benzene ring and the naphthalene ring system of adjacent mol-ecules links the mol-ecules into supra-molecular chains running along the b axis, the centroid-centroid distance being 3.765 (2) Å. ...[more]

PMID: 24046602

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