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Mild and general palladium-catalyzed synthesis of methyl aryl ethers enabled by the use of a palladacycle precatalyst.

ABSTRACT: A general method for the Pd-catalyzed coupling of methanol with (hetero)aryl halides is described. The reactions proceed under mild conditions with a wide range of aryl and heteroaryl halides to give methyl aryl ethers in high yield.

SUBMITTER: Cheung CW 

PROVIDER: S-EPMC3776604 | biostudies-literature | 2013 Aug

REPOSITORIES: biostudies-literature

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Mild and general palladium-catalyzed synthesis of methyl aryl ethers enabled by the use of a palladacycle precatalyst.

Cheung Chi Wai CW   Buchwald Stephen L SL  

Organic letters 20130724 15

A general method for the Pd-catalyzed coupling of methanol with (hetero)aryl halides is described. The reactions proceed under mild conditions with a wide range of aryl and heteroaryl halides to give methyl aryl ethers in high yield. ...[more]

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