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Utilizing tautomerization of 2-amino-oxazoline in hydrogen bonding tripodal ligands.

ABSTRACT: A tetradentate tripodal ligand containing 2-amino-oxazoline moieties has been developed. This system tautomerizes upon chelation of a metal ion, forming a flexible cavity capable of accommodating ligands via an intramolecular hydrogen bonding network.

SUBMITTER: Park YJ 

PROVIDER: S-EPMC3777267 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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Utilizing tautomerization of 2-amino-oxazoline in hydrogen bonding tripodal ligands.

Park Young Jun YJ   Sickerman Nathaniel S NS   Ziller Joseph W JW   Borovik A S AS  

Chemical communications (Cambridge, England) 20100311 15

A tetradentate tripodal ligand containing 2-amino-oxazoline moieties has been developed. This system tautomerizes upon chelation of a metal ion, forming a flexible cavity capable of accommodating ligands via an intramolecular hydrogen bonding network. ...[more]

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