Ontology highlight
ABSTRACT:
SUBMITTER: Cludius-Brandt S
PROVIDER: S-EPMC3778330 | biostudies-literature | 2013
REPOSITORIES: biostudies-literature
Cludius-Brandt Stephan S Kupracz Lukas L Kirschning Andreas A
Beilstein journal of organic chemistry 20130826
The photodenitrogenation of vinyl azides to 2H-azirines by using a photoflow reactor is reported and compared with thermal formation of 2H-azirines. Photochemically, the ring of the 2H-azirines was opened to yield the nitrile ylides, which underwent a [3 + 2]-cycloaddition with 1,3-dipolarophiles. When diisopropyl azodicarboxylate serves as the dipolarophile, 1,3,4-triazoles become directly accessible starting from the corresponding vinyl azide. ...[more]