Ontology highlight
ABSTRACT:
SUBMITTER: Sokol JG
PROVIDER: S-EPMC3786443 | biostudies-literature | 2013 Jun
REPOSITORIES: biostudies-literature
Sokol Joseph G JG Cochrane Nikki A NA Becker Jennifer J JJ Gagné Michel R MR
Chemical communications (Cambridge, England) 20130426 44
A series of phosphine-Pt(2+)-catalysts is reported, which enable the oxidative cascade cyclization of poly-alkene substrates. When the terminus is appropriately arranged and a catalyst reoxidation mediator is included, several polycyclic all carbon skeletons can be obtained. In one example, a chiral P2Pt(+2) catalyst provides up to 79% ee. ...[more]