Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Di-chlorido-diphenyl-bis-(thio-urea-?S)tin(IV).

ABSTRACT: The title compound, [Sn(C6H5)2Cl2(CH4N2S)2], has been obtained from the reaction between Sn(C6H5)2Cl2 and SC(NH2)2. The asymmetric unit consists of one half of the mol-ecular unit, the remainder generated by a twofold rotation axis located along the Cl-Sn-Cl bonds. The Sn(IV) atom is coordinated by two phenyl groups, two Cl atoms and two thio-urea ligands in an all trans octa-hedral C2Cl2S2 environment. Individual mol-ecules are connected through N-H?Cl hydrogen bonds, leading to a three-dimensional network structure. Intra-molecular N-H?Cl hydrogen bonds are also present.

SUBMITTER: Sow Y

PROVIDER: S-EPMC3790350 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Di-chlorido-diphenyl-bis-(thio-urea-κS)tin(IV).

Sow Yaya Y Diop Libasse L Molloy Kieran C KC Kociok-Köhn Gabriele G

Acta crystallographica. Section E, Structure reports online 20130912 Pt 10

The title compound, [Sn(C6H5)2Cl2(CH4N2S)2], has been obtained from the reaction between Sn(C6H5)2Cl2 and SC(NH2)2. The asymmetric unit consists of one half of the mol-ecular unit, the remainder generated by a twofold rotation axis located along the Cl-Sn-Cl bonds. The Sn(IV) atom is coordinated by two phenyl groups, two Cl atoms and two thio-urea ligands in an all trans octa-hedral C2Cl2S2 environment. Individual mol-ecules are connected through N-H⋯Cl hydrogen bonds, leading to a three-dimensi ...[more]

PMID: 24098172

Similar Datasets

Di-chlorido-dimethyl-bis-(thio-urea-κS)tin(IV).

Project description:The title compound, [Sn(CH3)2Cl2(CH4N2S)2], crystallizes with two half-mol-ecules in the asymmetric unit. Both mol-ecules are completed by inversion symmetry with the two Sn(IV) atoms located on inversion centers. The metal atoms have distorted octa-hedral coordination environments defined by two Cl atoms, two C atoms of methyl groups and two thio-urea S atoms. In the crystal, mol-ecules are linked via N-H⋯Cl and N-H⋯S hydrogen bonds, forming a three-dimensional structure.

| S-EPMC3998430 | biostudies-literature

μ(2)-Oxalato-bis-[triphen-yl(thio-urea-κS)tin(IV)].

Project description:The asymmetric unit of the binuclear title compound, [Sn(2)(C(2)O(4))(C(6)H(5))(6)(CH(4)N(2)S)(2)], consists of one half of the organotin(IV) mol-ecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C-C bond. The Sn(IV) atom exhibits a distorted trigonal-bipyramidal coordination environment with the phenyl groups in equatorial positions and the thio-urea and the monodentately bridging oxalate anion in axial positions. The mol-ecules are linked through N-H⋯O hydrogen bonds involving the amino group of the thio-urea ligand and the uncoordinating oxalate O atoms, forming layers parallel to (001). Weak C-H⋯O inter-actions are also present.

| S-EPMC3515101 | biostudies-literature

Di-?-hydroxido-bis-[dimeth-yl(thio-cyanato-?N)tin(IV)].

Project description:The Sn(IV) atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal-bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thio-cyanate anion are in the apical >positions. The dinuclear species are linked through O-H?S and C-H? S hydrogen-bonding inter-actions into a three-dimensional network.

| S-EPMC3588706 | biostudies-literature

Crystal structure of di-chlorido-bis-(N,N'-di-methyl-thio-urea-κS)mercury(II).

Project description:The mol-ecular structure of the title compound, [HgCl2(C3H8N2S)2], has point group symmetry 2, with the twofold rotation axis passing through the Hg(II) atom. The latter is coordinated by two Cl atoms and two N,N'-di-methyl-thio-urea (Dmtu) ligands through their S atoms, defining a distorted tetra-hedral coordination sphere with bond angles in the range 102.47 (4)-118.32 (4)°. Intra- and inter-molecular hydrogen bonds of the type N-H⋯Cl with S(6) and R 2 (2)(12) ring motifs are present. The inter-molecular contacts make up polymeric chains extending parallel to [101].

| S-EPMC4555414 | biostudies-literature

(4,7-Diphenyl-1,10-phenanthroline-κN,N')dimethyl-bis-(thio-cyanato-κN)tin(IV).

Project description:In the title compound, [Sn(CH(3))(2)(NSC)(2)(C(24)H(16)N(2))], a 1:1 adduct of dimethyl-tin diisothio-cyanate with 4,7-diphenyl-1,10-phenanthroline, the Sn(IV) atom shows a slightly distorted octa-hedral SnC(2)N(4) coordination. The methyl groups are trans to each other in the octa-hedron surrounding the metal atom [C-Sn-C = 176.61 (12)°].

| S-EPMC3051511 | biostudies-literature

Di-μ-methanolato-κO:O-bis[tri-chlorido(dimethyl-formamide-κO)tin(IV)].

Project description:The title compound, [Sn(2)(CH(3)O)(2)Cl(6)(C(3)H(7)NO)(2)], contains two hexa-coordinated Sn(IV) atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn(2)O(2) ring. The other sites of the distorted octa-hedral coordination geometry of the Sn(IV) atom are occupied by three Cl atoms and one O atom from a dimethyl-formamide mol-ecule. The complex mol-ecules are connected by weak C-H⋯Cl hydrogen bonds into a two-dimensional supra-molecular network parallel to (10).

| S-EPMC3051740 | biostudies-literature

Di-?-chlorido-bis-[diacetonitrile-chlorido-oxidovanadium(IV)].

Project description:The title compound, [V(2)Cl(4)O(2)(CH(3)CN)(4)], is a centrosymmetric dinuclear V(IV) complex associated with four mol-ecules of acetonitrile. The coordination around both V(IV) atoms is essentially square-planar, involving three Cl atoms and one O atom [maximum deviation = 0.017?(3)?Å for the O atom]. The augmented octahedral coordination of the metal atom is completed by the N atoms of acetonitrile ligands. The V(IV) atoms are linked by two Cl atoms, acting as bridging atoms. The crystal studied was a non-merohedral twin with a ratio of the two twin components of 0.8200?(3):0.1800?(3). Although Cl and O atoms are present as potential acceptors in the title compound, no hydrogen bonds were observed in the crystal structure.

| S-EPMC3201240 | biostudies-literature

(1,5-Diphenyl-thio-carbazonato-?S)trimethyl-tin(IV).

Project description:In the title compound, [Sn(C13H11N4S)(CH3)3], the Sn(IV) atom is coordinated by an S atom from the 1,5-diphenyl-thio-carbazonato (L) ligand [Sn-S 2.4710?(6)?Å] and by three methyl groups [Sn-C 2.123?(3)-2.130?(2)?Å] in a distorted tetra-hedral geometry. The aromatic rings of the L ligand form a dihedral angle of 2.1?(1)°.

| S-EPMC3588764 | biostudies-literature

Bis(μ-disulfur dinitrido)bis-[diphenyl-tin(IV)].

Project description:The title compound, [Sn(2)(C(6)H(5))(4)(N(2)S(2))(2)], exists as a centrosymmetric binuclear dimer with the Sn(IV) centres in distorted trigonal bipyramidal geometry and a central Sn(2)N(2) core.

| S-EPMC2961121 | biostudies-literature

Di-n-butyl-bis-(thio-cyanato-κN)(1,10-phenanthroline-κN,N')tin(IV).

Project description:In the asymmetric unit of the title compound, [Sn(C(4)H(9))(2)(NCS)(2)(C(12)H(8)N(2))], there are two independent mol-ecules, both lying on a twofold rotation axis. The axis passes through the mid-point of the 1,10 and 5,6 bonds of the N-heterocycle and through the Sn atom. The Sn atoms show a slightly distorted SnC(2)N(4) octa-hedral coordination.

| S-EPMC3051678 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data