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Di-chlorido-diphenyl-bis-(thio-urea-?S)tin(IV).

ABSTRACT: The title compound, [Sn(C6H5)2Cl2(CH4N2S)2], has been obtained from the reaction between Sn(C6H5)2Cl2 and SC(NH2)2. The asymmetric unit consists of one half of the mol-ecular unit, the remainder generated by a twofold rotation axis located along the Cl-Sn-Cl bonds. The Sn(IV) atom is coordinated by two phenyl groups, two Cl atoms and two thio-urea ligands in an all trans octa-hedral C2Cl2S2 environment. Individual mol-ecules are connected through N-H?Cl hydrogen bonds, leading to a three-dimensional network structure. Intra-molecular N-H?Cl hydrogen bonds are also present.

SUBMITTER: Sow Y

PROVIDER: S-EPMC3790350 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Di-chlorido-diphenyl-bis-(thio-urea-κS)tin(IV).

Sow Yaya Y Diop Libasse L Molloy Kieran C KC Kociok-Köhn Gabriele G

Acta crystallographica. Section E, Structure reports online 20130912 Pt 10

The title compound, [Sn(C6H5)2Cl2(CH4N2S)2], has been obtained from the reaction between Sn(C6H5)2Cl2 and SC(NH2)2. The asymmetric unit consists of one half of the mol-ecular unit, the remainder generated by a twofold rotation axis located along the Cl-Sn-Cl bonds. The Sn(IV) atom is coordinated by two phenyl groups, two Cl atoms and two thio-urea ligands in an all trans octa-hedral C2Cl2S2 environment. Individual mol-ecules are connected through N-H⋯Cl hydrogen bonds, leading to a three-dimensi ...[more]

PMID: 24098172

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