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(O-Methyl di-thio-carbonato-κS)tri-phenyl-tin(IV).

ABSTRACT: In the title compound, [Sn(C6H5)3(C2H3OS2)], the Sn(IV) atom adopts a distorted SnC3S tetra-hedral coordination geometry. A short Sn⋯O contact [2.988 (4) Å] is also present. The phenyl rings are each disordered over two sets of sites with an occupancy ratio of 0.550 (8):0.450 (8). The crystal studied was found to be a racemic twin with a twin component ratio of 0.57 (18):0.43 (18).

SUBMITTER: Javed F

PROVIDER: S-EPMC3684880 | biostudies-literature | 2013 Jun

REPOSITORIES: biostudies-literature

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(O-Methyl di-thio-carbonato-κS)tri-phenyl-tin(IV).

Javed Fatima F Ali Saqib S Shah Wajid W Tahir M Nawaz MN Ullah Hameed H

Acta crystallographica. Section E, Structure reports online 20130515 Pt 6

In the title compound, [Sn(C6H5)3(C2H3OS2)], the Sn(IV) atom adopts a distorted SnC3S tetra-hedral coordination geometry. A short Sn⋯O contact [2.988 (4) Å] is also present. The phenyl rings are each disordered over two sets of sites with an occupancy ratio of 0.550 (8):0.450 (8). The crystal studied was found to be a racemic twin with a twin component ratio of 0.57 (18):0.43 (18). ...[more]

PMID: 23794982

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