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Poly[?5-(4-meth-oxy-benzene-sulfonato)-sodium].

ABSTRACT: In the title complex, [Na(C7H7O4S)] n , the Na(I) ion is coord-inated in a slightly distorted penta-gonal-bipyramidal environment by seven O atoms [Na-O = 2.3198?(16)-2.5585?(17)?Å]. The 4-methoxybenzenesulfonate anions act as bis-chelating and bridging ligands, forming a two-dimensional polymer parallel to (001), which is further linked into a three-dimensional network by weak C-H?O hydrogen bonds.

SUBMITTER: Chantrapromma S

PROVIDER: S-EPMC3790362 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Poly[μ5-(4-meth-oxy-benzene-sulfonato)-sodium].

Chantrapromma Suchada S Boonnak Nawong N Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20130925 Pt 10

In the title complex, [Na(C7H7O4S)] n , the Na(I) ion is coord-inated in a slightly distorted penta-gonal-bipyramidal environment by seven O atoms [Na-O = 2.3198 (16)-2.5585 (17) Å]. The 4-methoxybenzenesulfonate anions act as bis-chelating and bridging ligands, forming a two-dimensional polymer parallel to (001), which is further linked into a three-dimensional network by weak C-H⋯O hydrogen bonds. ...[more]

PMID: 24098184

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