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Poly[?(2)-aqua-(?(3)-2,5-dichloro-benzene-sulfonato)sodium].

ABSTRACT: In the title compound, [Na(C(6)H(3)Cl(2)O(3)S)(H(2)O)](n), the Na(I) ion is penta-coordinated by three dichloro-benzene-sulfonate anions and two water mol-ecules, forming a distorted trigonal-bipyramidal geometry. The Na(I) ions are bridged by the sulfonate groups and the water mol-ecules, leading to a polymeric layer structure parallel to the bc plane in which O-H?O hydrogen bonds are observed.

SUBMITTER: Al-Dajani MT

PROVIDER: S-EPMC2979400 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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Poly[μ(2)-aqua-(μ(3)-2,5-dichloro-benzene-sulfonato)sodium].

Al-Dajani Mohammad T M MT Abdallah Hassan H HH Mohamed Nornisah N Yeap Chin Sing CS Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20100522 Pt 6

In the title compound, [Na(C(6)H(3)Cl(2)O(3)S)(H(2)O)](n), the Na(I) ion is penta-coordinated by three dichloro-benzene-sulfonate anions and two water mol-ecules, forming a distorted trigonal-bipyramidal geometry. The Na(I) ions are bridged by the sulfonate groups and the water mol-ecules, leading to a polymeric layer structure parallel to the bc plane in which O-H⋯O hydrogen bonds are observed. ...[more]

PMID: 21579334

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