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Tri-aqua-(pyrazole-4-carboxyl-ato-?N (1))lithium.

ABSTRACT: In the monomeric title complex, [Li(C4H3N2O2)(H2O)3], the Li(+) cation is coordinated by a pyrazole N atom and three water mol-ecules in a distorted tetra-hedral geometry. The carboxyl-ate group is deprotonated. The complex mol-ecules are involved in O-H?O and N-H?O hydrogen bonding, forming layers stacked along the b axis.

SUBMITTER: Starosta W

PROVIDER: S-EPMC3793681 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Tri-aqua-(pyrazole-4-carboxyl-ato-κN (1))lithium.

Starosta Wojciech W Leciejewicz Janusz J

Acta crystallographica. Section E, Structure reports online 20130706 Pt 8

In the monomeric title complex, [Li(C4H3N2O2)(H2O)3], the Li(+) cation is coordinated by a pyrazole N atom and three water mol-ecules in a distorted tetra-hedral geometry. The carboxyl-ate group is deprotonated. The complex mol-ecules are involved in O-H⋯O and N-H⋯O hydrogen bonding, forming layers stacked along the b axis. ...[more]

PMID: 24109268

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