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Bis[?-3,5-bis-(pyridin-2-yl)pyrazolato]bis-[(hexa-fluoro-phosphato)copper(II)].

ABSTRACT: The title dinuclear complex mol-ecule, [Cu2(C13H9N4)2(PF6)2], lies about an inversion center. The Cu(II) atom shows a square-pyramidal coordination geometry with the basal plane formed by four N atoms of the two bis-chelating 3,5-bis-(pyridin-2-yl)pyrazolate ions and with one F atom of the hexa-fluoro-phosphate ion in the apical position. Mol-ecules are stacked in a column along the a axis through C-H?F hydrogen bonds. The columns are further linked by other C-H?F hydrogen bonds, forming a three-dimensional network.

SUBMITTER: Mishima A

PROVIDER: S-EPMC3793691 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Bis[μ-3,5-bis-(pyridin-2-yl)pyrazolato]bis-[(hexa-fluoro-phosphato)copper(II)].

Mishima Akio A Katsuta Nagisa N Furusyou Midori M Fuyuhiro Akira A Kawata Satoshi S

Acta crystallographica. Section E, Structure reports online 20130713 Pt 8

The title dinuclear complex mol-ecule, [Cu2(C13H9N4)2(PF6)2], lies about an inversion center. The Cu(II) atom shows a square-pyramidal coordination geometry with the basal plane formed by four N atoms of the two bis-chelating 3,5-bis-(pyridin-2-yl)pyrazolate ions and with one F atom of the hexa-fluoro-phosphate ion in the apical position. Mol-ecules are stacked in a column along the a axis through C-H⋯F hydrogen bonds. The columns are further linked by other C-H⋯F hydrogen bonds, forming a three ...[more]

PMID: 24109278

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