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Thio-phene-2-carbonyl azide.

ABSTRACT: The title compound, C5H3N3OS, is almost planar (r.m.s. deviation for the ten non-H atoms = 0.018?Å) and forms an extended layer structure in the (100) plane, held together via hydrogen-bonding inter-actions between adjacent mol-ecules. Of particular note is the occurrence of RC-H?N(-)=N(+)=NR inter-actions between an aromatic C-H group and an azide moiety which, in conjunction with a complementary C-H?O=C inter-action, forms a nine-membered ring.

SUBMITTER: Hsu GC

PROVIDER: S-EPMC3793789 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Thio-phene-2-carbonyl azide.

Hsu Gene C GC Singer Laci M LM Cordes David B DB Findlater Michael M

Acta crystallographica. Section E, Structure reports online 20130724 Pt 8

The title compound, C5H3N3OS, is almost planar (r.m.s. deviation for the ten non-H atoms = 0.018 Å) and forms an extended layer structure in the (100) plane, held together via hydrogen-bonding inter-actions between adjacent mol-ecules. Of particular note is the occurrence of RC-H⋯N(-)=N(+)=NR inter-actions between an aromatic C-H group and an azide moiety which, in conjunction with a complementary C-H⋯O=C inter-action, forms a nine-membered ring. ...[more]

PMID: 24109376

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