Ontology highlight
ABSTRACT:
SUBMITTER: Kabehie S
PROVIDER: S-EPMC3800170 | biostudies-literature | 2010 Nov
REPOSITORIES: biostudies-literature
Kabehie Sanaz S Xue Mei M Stieg Adam Z AZ Liong Monty M Wang Kang L KL Zink Jeffrey I JI
Journal of the American Chemical Society 20101022 45
Heteroleptic copper compounds have been designed and synthesized on solid supports. Chemical redox agents were used to change the oxidation state of the SiO(2)-immobilized heteroleptic copper compounds from Cu(I) to Cu(II) and then back to Cu(I). Optical spectroscopy of a dimethyl sulfoxide suspension demonstrated the reversibility of the Cu(I)/Cu(II) SiO(2)-immobilized compounds by monitoring the metal-to-ligand charge transfer peak at about 450 nm. Electron paramagnetic resonance spectroscopy ...[more]