Ontology highlight
ABSTRACT:
SUBMITTER: Rhodes NR
PROVIDER: S-EPMC3821766 | biostudies-literature | 2013 Nov
REPOSITORIES: biostudies-literature
Polyhedron 20131101
The synthesis and characterization of chromium basic carboxylate complexes, [Cr<sub>3</sub>(O<sub>2</sub>CR)<sub>6</sub>L<sub>3</sub>]<sup>+</sup>, containing trifluoroacetate, 3-fluoropyridine, 3-trifluoromethylpyridine, and 4-trifluoromethylpyridine are described. The substituted pyridine ligands are used as models of DNA bases to determine whether <sup>19</sup>F NMR would be a potentially useful probe of the binding of Cr<sup>3+</sup> to DNA. The <sup>19</sup>F NMR resonances of the coordinat ...[more]