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Trans-Di-fluorido-tetra-kis-(pyridine-?N)chromium(III) perchlorate from synchrotron radiation.

ABSTRACT: The are two independent complex cations in the title salt, [CrF2(C5H5N)4]ClO4, each located on a centre of inversion, as well as an independent perchlorate counter-ion. The complex cations adopt slightly distorted octa-hedral coordination environments around the Cr(III) ion, defined by four pyridine (py) N atoms in the equatorial plane and two F(-) ligands in the axial positions; intra-molecular C-H?F contacts are noted. The mean Cr-N(py) and Cr-F bond lengths are 2.088?(6) and 1.8559?(10)?Å, respectively. The three-dimensional architecture is sustained by hydrogen bonds involving the pyridine C-H groups as donors, and F and O atoms as acceptors.

SUBMITTER: Moon D

PROVIDER: S-EPMC3884409 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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trans-Di-fluorido-tetra-kis-(pyridine-κN)chromium(III) perchlorate from synchrotron radiation.

Moon Dohyun D Choi Jong-Ha JH

Acta crystallographica. Section E, Structure reports online 20130823 Pt 9

The are two independent complex cations in the title salt, [CrF2(C5H5N)4]ClO4, each located on a centre of inversion, as well as an independent perchlorate counter-ion. The complex cations adopt slightly distorted octa-hedral coordination environments around the Cr(III) ion, defined by four pyridine (py) N atoms in the equatorial plane and two F(-) ligands in the axial positions; intra-molecular C-H⋯F contacts are noted. The mean Cr-N(py) and Cr-F bond lengths are 2.088 (6) and 1.8559 (10) Å, re ...[more]

PMID: 24427004

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