Ontology highlight
ABSTRACT:
SUBMITTER: An P
PROVIDER: S-EPMC3854928 | biostudies-literature | 2013 Nov
REPOSITORIES: biostudies-literature
An Peng P Yu Zhipeng Z Lin Qing Q
Organic letters 20131010 21
The design and synthesis of a new class of laser light activatable tetrazoles with extended π-systems is reported. Upon 405 nm laser light irradiation, these bithiophene-substituted tetrazoles underwent extremely fast 1,3-dipolar cycloaddition reactions with dimethyl fumarate with second-order rate constants approaching 4000 M(-1) s(-1). The resulting pyrazoline cycloadducts exhibited solvent-dependent red fluorescence, making these tetrazoles potentially useful as fluorogenic probes for detecti ...[more]