Dataset Information
Sterically shielded tetrazoles for a fluorogenic photoclick reaction: tuning cycloaddition rate and product fluorescence.
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ABSTRACT:
SUBMITTER: An P
PROVIDER: S-EPMC6059988 | biostudies-literature | 2018 Jul
REPOSITORIES: biostudies-literature
Publications
Sterically shielded tetrazoles for a fluorogenic photoclick reaction: tuning cycloaddition rate and product fluorescence.
Organic & biomolecular chemistry 20180701 29
A panel of sterically shielded tetrazoles with different N-aryl groups were synthesized and subsequently evaluated in the photoinduced tetrazole-alkene cycloaddition reaction. It was found that increase in the HOMO energy of the corresponding nitrile imines leads to a faster cycloaddition reaction along with a red shift in the fluorescence emission of the pyrazoline cycloadduct. ...[more]