Ontology highlight
ABSTRACT:
SUBMITTER: Willumstad TP
PROVIDER: S-EPMC3861882 | biostudies-literature | 2013 Nov
REPOSITORIES: biostudies-literature
The Journal of organic chemistry 20131028 22
Highly substituted polycyclic aromatic and heteroaromatic compounds are produced via a two-stage tandem benzannulation/cyclization strategy. The initial benzannulation step proceeds via a pericyclic cascade mechanism triggered by thermal or photochemical Wolff rearrangement of a diazo ketone. The photochemical process can be performed using a continuous flow reactor which facilitates carrying out reactions on a large scale and minimizes the time required for photolysis. Carbomethoxy ynamides as ...[more]