Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Highly efficient plastic crystal ionic conductors for solid-state dye-sensitized solar cells.

ABSTRACT: We have developed highly efficient, ambient temperature, solid-state ionic conductors (SSICs) for dye-sensitized solar cells (DSSCs) by doping a molecular plastic crystal, succinonitrile (SN), with trialkyl-substituted imidazolium iodide salts. High performance SSICs with enhanced ionic conductivity (2-4?mScm?¹) were obtained. High performance solid-state DSSCs with power conversion efficiency of 7.8% were fabricated using our SSICs combined with unique hierarchically nanostructured TiO? sphere (TiO?-SP) photoelectrodes; these electrodes have significant macroporosity, which assists penetration of the solid electrolyte into the electrode. The performance of our solid-state DSSCs is, to the best of our knowledge, the highest reported thus far for cells using plastic crystal-based SSICs, and is comparable to that of the state-of-the-art DSSCs which use ionic liquid type electrolytes. This report provides a logical strategy for the development of efficient plastic crystal-based SSICs for DSSCs and other electrochemical devices.

SUBMITTER: Hwang D

PROVIDER: S-EPMC3865487 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Blue-coloured highly efficient dye-sensitized solar cells by implementing the diketopyrrolopyrrole chromophore.

Project description:The paradigm shift in dye sensitized solar cells (DSCs) - towards donor- ? bridge-acceptor (D-?-A) dyes - increases the performances of DSCs and challenges established design principles. Framed by this shifting landscape, a series of four diketopyrrolopyrrole (DPP)-based sensitizers utilizing the donor-chromophore-anchor (D-C-A) motif were investigated computationally, spectroscopically, and fabricated by systematic evaluation of finished photovoltaic cells. In all cases, the [Co(bpy)3](3+/2+) redox-shuttle afforded superior performance compared to I3(-)/I(-). Aesthetically, careful molecular engineering of the DPP chromophore yielded the first example of a high-performance blue DSC - a challenge unmet since the inception of this photovoltaic technology: DPP17 yields over 10% power conversion efficiency (PCE) with the [Co(bpy)3](3+/2+) electrolyte at full AM 1.5 G simulated sun light.

| S-EPMC3744082 | biostudies-other

Highly-Efficient Plasmon-Enhanced Dye-Sensitized Solar Cells Created by Means of Dry Plasma Reduction.

Project description:Plasmon-assisted energy conversion is investigated in a comparative study of dye-sensitized solar cells (DSCs) equipped with photo-anodes, which are fabricated by forming gold (Au) and silver (Ag) nanoparticles (NPs) on an fluorine-doped tin oxide (FTO) glass surface by means of dry plasma reduction (DPR) and coating TiO? paste onto the modified FTO glass through a screen printing method. As a result, the FTO/Ag-NPs/TiO? photo-anode showed an enhancement of its photocurrent, whereas the FTO/Au-NPs/TiO? photo-anode showed less photocurrent than even a standard photo-anode fabricated by simply coating TiO? paste onto the modified FTO glass through screen printing. This result stems from the small size and high areal number density of Au-NPs on FTO glass, which prevent the incident light from reaching the TiO? layer.

| S-EPMC5302568 | biostudies-literature

Novel and Stable D-A-π-A Dyes for Efficient Solid-State Dye-Sensitized Solar Cells.

Project description:Two novel organic donor-acceptor-π-acceptor sensitizers, W7 and W8, have been applied in efficient solid-state dye-sensitized solar cells (ssDSSCs). Using 2,2',7,7'-tetrakis(N,N-di-p-methoxyphenyl-amine) 9,9'-spirobifluorene (Spiro-OMeTAD) as hole-transport material (HTM), an excellent power conversion efficiency of 6.9% was recorded for W7, together with an excellent photocurrent of 10.51 mA cm-2 and a high open-circuit voltage of 880 mV under standard AM 1.5 G illumination (100 mW cm-2). The solid-state solar cells based on W8 showed an efficiency of 5.2%, with a good photocurrent of 9.55 mA cm-2 and an open-circuit voltage of 870 mV. Compared to that of the well-known WS2 sensitizer, the results show that the performance of the ssDSSC devices can be significantly improved by introducing triphenylamine moiety into their structure. In addition, results of photoinduced absorption spectroscopy show efficient dye regeneration for W7- and W8-based devices. A higher hole conductivity of the W7/HTM and W8/HTM layers compared to that of the WS2/HTM layer was observed, indicating an efficient charge transfer at the interfaces. The results obtained offer insights into the design of reliable and highly efficient ssDSSCs for large-scale applications.

| S-EPMC6640992 | biostudies-literature

Angular response of photonic crystal based dye sensitized solar cells.

Project description:Herein we report an experimental analysis of the performance of photonic crystal based dye solar cells (PC-DSCs) as the incident light angle moves away from the normal with respect to the cell surface. Nanoparticle multilayers operating at different wavelength ranges were coupled to the working electrode of a dye solar cell for this study. The interplay between optical and photovoltaic properties with the incident light angle is discussed. We demonstrate that an efficiency enhancement is attained for PC-DSCs at all angles measured, and that rational design of the photonic crystal back mirror leads to a reduction of the photocurrent losses related to the tilt angle of the cell, usually labeled as cosine losses. Angular variations of the cell transparency are also reported and discussed. These angular properties are relevant to the application of these solar devices in building integrated photovoltaics as potential window modules.

| S-EPMC4535183 | biostudies-literature

Efficient bifacial dye-sensitized solar cells through disorder by design.

Project description:Herein we realize an optical design that optimizes the performance of bifacial solar cells without modifying any of the usually employed components. In order to do so, dielectric scatterers of controlled size and shape have been successfully integrated in the working electrodes of dye-sensitized solar cells (DSSCs), resulting in bifacial devices of outstanding performance. Power conversion efficiencies (PCEs) as high as 6.7% and 5.4% have been attained under front and rear illumination, respectively, which represent a 25% and a 33% PCE enhancement with respect to an 8 μm-thick standard solar cell electrode using platinum as the catalytic material. The remarkable bifacial character of our approach is demonstrated by the high rear/front efficiency ratio attained, around 80%, which is among the largest reported for this sort of device. The proposed optimized design is based on a Monte Carlo approach in which the multiple scattering of light within the cell is fully accounted for. We identified that the spherical shape of the scatterers is the key parameter controlling the angular distribution of the scattering, the most efficient devices being those in which the inclusions provide a narrow forward-oriented angular distribution of the scattered light.

| S-EPMC4786952 | biostudies-literature

Erratum: Novel and Stable D-A-π-A Dyes for Efficient Solid-State Dye-Sensitized Solar Cells.

Project description:[This corrects the article DOI: 10.1021/acsomega.7b00067.].

| S-EPMC6645414 | biostudies-literature

Highly stable tandem solar cell monolithically integrating dye-sensitized and CIGS solar cells.

Project description:UnlabelledA highly stable monolithic tandem solar cell was developed by combining the heterogeneous photovoltaic technologies of dye-sensitized solar cell (DSSC) and solution-processed CuInxGa1-xSeyS1-y (CIGS) thin film solar cells. The durability of the tandem cell was dramatically enhanced by replacing the redox couple from to [Co(bpy)3](2+) /[Co(bpy)3](3+)), accompanied by a well-matched counter electrode (PedotPSS) and sensitizer (Y123). A 1000 h durability test of the DSSC/CIGS tandem solar cell in ambient conditions resulted in only a 5% decrease in solar cell efficiency. Based on electrochemical impedance spectroscopy and photoelectrochemical cell measurement, the enhanced stability of the tandem cell is attributed to minimal corrosion by the cobalt-based polypyridine complex redox couple.

| S-EPMC4973243 | biostudies-literature

Cellulose Nanocrystal Aerogels as Electrolyte Scaffolds for Glass and Plastic Dye-Sensitized Solar Cells.

Project description:The fabrication, thickness, and structure of aerogel films composed of covalently cross-linked cellulose nanocrystals (CNCs) and poly(oligoethylene glycol methacrylate) (POEGMA) were optimized for use as electrolyte absorbers in dye-sensitized solar cells (DSSCs). The aerogel films were cast directly on transparent conducting counter electrode substrates (glass and flexible poly(ethylene terephthalate) plastic) and then used to absorb drop-cast liquid electrolyte, thus providing an alternative method of filling electrolyte in DSSCs. This approach eliminates the use of electrolyte-filling holes, which are a typical pathway of electrolyte leakage, and furthermore enables a homogeneous distribution of electrolyte components within the photoelectrode. Unlike typical in situ electrolyte gelation approaches, the phase inversion method used here results in a highly porous (>99%) electrolyte scaffold with excellent ionic conductivity and interfacial properties. DSSCs prepared with CNC-POEGMA aerogels reached similar power conversion efficiencies as compared to liquid electrolyte devices, indicating that the aerogel does not interfere with the operation of the device. These aerogels retain their structural integrity upon bending, which is critical for their application in flexible devices. Furthermore, the aerogels demonstrate impressive chemical and mechanical stability in typical electrolyte solvents because of their stable covalent cross-linking. Overall, this work demonstrates that the DSSC fabrication process can be simplified and made more easily upscalable by taking advantage of CNCs, being an abundant and sustainable bio-based material.

| S-EPMC6752057 | biostudies-literature

Multifunctional interface modification of energy relay dye in quasi-solid dye-sensitized solar cells.

Project description:In this paper, 4-(dicyanomethylene)-2-t-butyl-6(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTB) has been used in interface modification of dye-sensitized solar cells (DSCs) with combined effects of retarding charge recombination and Förster resonant energy transfer (FRET). DCJTB interface modification significantly improved photovoltaic performance of DSCs. I-V curves shows the conversion efficiency increases from 4.27% to 5.64% with DCJTB coating. The application of DCJTB with combined effects is beneficial to explore more novel multi-functional interface modification materials to improve the performance of DSCs.

| S-EPMC4081872 | biostudies-other

Recovering degraded quasi-solid-state dye-sensitized solar cells by applying electrical pulses.

Project description:We discovered a method of applying a forward pulsed bias to recover the degraded quasi-solid-state dye-sensitized solar cells (DSSCs). Up to 30.7% of the power conversion efficiency (?) of a degraded poly(vinylidene fluoride) (PVDF) based DSSC was recovered by a double-pulse. The recovered ? remained higher than that before the double-pulse treatment for at least 28 days. It is deduced that the blocking of ion-transport channels in the quasi-solid-state electrolyte causes degradation of the DSSCs. This study will shed light on the efficiency enhancement and long-term stability of quasi-solid-state DSSCs.

| S-EPMC3650726 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data