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Bis(?-l-arginine-?(3) N (2),O:O')bis-(l-arginine-?(2) N (2),O)tetra-?-chlorido-tetra-chlorido-tetra-copper(II).

ABSTRACT: The title compound, [Cu4Cl8(C6H14N4O2)4], contains four mol-ecules in the asymmetric unit. In the mol-ecular structure, each of the four Cu(2+) ions binds to three Cl atoms, one N atom and one O atom, resulting in distorted square-pyramidal coordination environments. The molecular structure is stabilized by weak C-H?O and N-H?Cl hydrogen bonds. The crystal structure exhibit weak inter-molecular N-H?O, C-H?O and N-H?Cl inter-actions, generating a three-dimensional network.

SUBMITTER: Arularasan P

PROVIDER: S-EPMC3884247 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature

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Bis(μ-l-arginine-κ(3) N (2),O:O')bis-(l-arginine-κ(2) N (2),O)tetra-μ-chlorido-tetra-chlorido-tetra-copper(II).

Arularasan P P B Sivakumar Chakkaravarthi G G Mohan R R

Acta crystallographica. Section E, Structure reports online 20131005 Pt 11

The title compound, [Cu4Cl8(C6H14N4O2)4], contains four mol-ecules in the asymmetric unit. In the mol-ecular structure, each of the four Cu(2+) ions binds to three Cl atoms, one N atom and one O atom, resulting in distorted square-pyramidal coordination environments. The molecular structure is stabilized by weak C-H⋯O and N-H⋯Cl hydrogen bonds. The crystal structure exhibit weak inter-molecular N-H⋯O, C-H⋯O and N-H⋯Cl inter-actions, generating a three-dimensional network. ...[more]

PMID: 24454023

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