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?-Adipato-bis-[chlorido(2,2':6',2''-terpyridine)-copper(II)] tetra-hydrate.

ABSTRACT: In the title compound, [Cu(2)(C(6)H(8)O(4))Cl(2)(C(15)H(11)N(3))(2)]·4H(2)O, the dinuclear copper complex is located on a crystallographic inversion centre. Each Cu atom is in a distorted square-pyramidal coordination environment, with one O atom of an adipate dianion and three N atoms from the 2,2':6',2''-terpyridine ligand occupying the basal plane, and one chlorine in the apical site. In addition, there is weak Cu-O inter-action opposite of the chlorine with a distance of 2.768?(1)?Å. The adipate ligand adopts a gauche-anti-gauche conformation. The inter-stitial water mol-ecules form hydrogen-bonded tertramers that are connected to the complexes via O-H?O and O-H?Cl hydrogen bonds, thus leading to the formation of tightly hydrogen-bonded layers extending perpendicular to the b-axis direction.

SUBMITTER: Xie HZ

PROVIDER: S-EPMC3007253 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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μ-Adipato-bis-[chlorido(2,2':6',2''-terpyridine)-copper(II)] tetra-hydrate.

Xie Hong-Zhen HZ Zhang Yan-Guang YG

Acta crystallographica. Section E, Structure reports online 20100714 Pt 8

In the title compound, [Cu(2)(C(6)H(8)O(4))Cl(2)(C(15)H(11)N(3))(2)]·4H(2)O, the dinuclear copper complex is located on a crystallographic inversion centre. Each Cu atom is in a distorted square-pyramidal coordination environment, with one O atom of an adipate dianion and three N atoms from the 2,2':6',2''-terpyridine ligand occupying the basal plane, and one chlorine in the apical site. In addition, there is weak Cu-O inter-action opposite of the chlorine with a distance of 2.768 (1) Å. The adi ...[more]

PMID: 21588166

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