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N-(2-Chloro-acet-yl)glycine.

ABSTRACT: The title compound, C4H6ClNO3, crystallizes with two independent mol-ecules (A and B) in the asymmetric unit. In each mol-ecule, there are N-H?O and N-H?Cl hydrogen bonds. Both mol-ecules are relatively planar, with the mean plane of the acetamide [N-C(=O)C] group being inclined to the mean plane of the acetate group [C-C(=O)O] by 9.23?(13)° in mol-ecule A and 6.23?(12)° in mol-ecule B. In the crystal, adjacent mol-ecules are linked by O-H?O hydrogen bonds and weak C-H?O contacts forming -A-A-A- and -B-B-B- parallel chains propagating along the a-axis direction.

SUBMITTER: Zhang YC

PROVIDER: S-EPMC3884360 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature

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N-(2-Chloro-acet-yl)glycine.

Zhang Yu-Cheng YC Zhang Xiu-Qin XQ Wang Kai K Chen Qiang Q

Acta crystallographica. Section E, Structure reports online 20131026 Pt 11

The title compound, C4H6ClNO3, crystallizes with two independent mol-ecules (A and B) in the asymmetric unit. In each mol-ecule, there are N-H⋯O and N-H⋯Cl hydrogen bonds. Both mol-ecules are relatively planar, with the mean plane of the acetamide [N-C(=O)C] group being inclined to the mean plane of the acetate group [C-C(=O)O] by 9.23 (13)° in mol-ecule A and 6.23 (12)° in mol-ecule B. In the crystal, adjacent mol-ecules are linked by O-H⋯O hydrogen bonds and weak C-H⋯O contacts forming -A-A-A- ...[more]

PMID: 24454136

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