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N'-[(E)-2-Fluoro-benzyl-idene]benzo-hydrazide.

ABSTRACT: The asymmetric unit of the title compound, C14H11FN2O, contains two independent mol-ecules, both of which adopt the E conformation with respect to the azomethine C=N bond. The mol-ecules are non-planar, with dihedral angles of 26.92?(12) and 11.36?(11)° between the benzene and phenyl rings. In the crystal, mol-ecules are linked through N-H?O=C and N-H?N hydrogen bonds into chains along [101]. C-H?O contacts link these chains into layers parallel to (001). The three-dimensional crystal packing is stabilized by ?-? inter-actions, the shortest separation between the centroids of benzene rings being 3.884?(1)?Å.

SUBMITTER: Sreeja PB 

PROVIDER: S-EPMC3885076 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature

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N'-[(E)-2-Fluoro-benzyl-idene]benzo-hydrazide.

Sreeja P B PB   Sithambaresan M M   Aiswarya N N   Kurup M R Prathapachandra MR  

Acta crystallographica. Section E, Structure reports online 20131127 Pt 12

The asymmetric unit of the title compound, C14H11FN2O, contains two independent mol-ecules, both of which adopt the E conformation with respect to the azomethine C=N bond. The mol-ecules are non-planar, with dihedral angles of 26.92 (12) and 11.36 (11)° between the benzene and phenyl rings. In the crystal, mol-ecules are linked through N-H⋯O=C and N-H⋯N hydrogen bonds into chains along [101]. C-H⋯O contacts link these chains into layers parallel to (001). The three-dimensional crystal packing is  ...[more]

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