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N,N,2,4,6-Penta-methyl-anilinium hexa-fluoro-phosphate-1,4,7,10,13,16-hexa-oxa-cyclo-octa-decane (2/1).

ABSTRACT: In the title compound, 2C11H18N(+)·2PF6 (-)·C12H24O6, the 18-crown-6 mol-ecule has crystallographically imposed inversion symmetry. In the crystal, it inter-acts with the cation through weak C-H?O hydrogen bonds. The cations and anions are further linked via N-H?F and C-H?F hydrogen bonds, leading to a sandwich structure .

SUBMITTER: Chang YQ

PROVIDER: S-EPMC3914100 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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N,N,2,4,6-Penta-methyl-anilinium hexa-fluoro-phosphate-1,4,7,10,13,16-hexa-oxa-cyclo-octa-decane (2/1).

Chang Yi Qi YQ Zhang Yuan Y Lian Huo Lin HL

Acta crystallographica. Section E, Structure reports online 20131218 Pt 1

In the title compound, 2C11H18N(+)·2PF6 (-)·C12H24O6, the 18-crown-6 mol-ecule has crystallographically imposed inversion symmetry. In the crystal, it inter-acts with the cation through weak C-H⋯O hydrogen bonds. The cations and anions are further linked via N-H⋯F and C-H⋯F hydrogen bonds, leading to a sandwich structure . ...[more]

PMID: 24527005

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