Ontology highlight
ABSTRACT:
SUBMITTER: Maroto EE
PROVIDER: S-EPMC3914395 | biostudies-literature | 2014 Jan
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20140103 2
A wide range of new dipoles and catalysts have been used in 1,3-dipolar cycloadditions of N-metalated azomethine ylides onto C60 yielding a full stereodivergent synthesis of pyrrolidino[60]fullerenes with complete diastereoselectivities and very high enantioselectivities. The use of less-explored chiral α-iminoamides as starting 1,3-dipoles leads to an interesting double asymmetric induction resulting in a matching/mismatching effect depending upon the absolute configuration of the stereocenter ...[more]