Ontology highlight
ABSTRACT:
SUBMITTER: Schulte ML
PROVIDER: S-EPMC3925759 | biostudies-literature | 2013 Sep
REPOSITORIES: biostudies-literature
Chemistry (Weinheim an der Bergstrasse, Germany) 20130816 36
Winning the relay: The first total synthesis of stemaphylline N-oxide has been completed utilizing a bistandem relay ring-closing-metathesis (RRCM) strategy, necessitated by the conformation of the requisite tetraene. This effort also gave unnatural 9a-epi-stemaphylline and 9a-epi-stemaphylline N-oxide. ...[more]