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Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction.

ABSTRACT: This study describes a heteroligated, hemilabile Pt(II)-P,S tweezer coordination complex that combines a chiral Jacobsen-Katsuki Mn(III)-salen epoxidation catalyst with an amidopyridine receptor, which leads to an inversion of the major epoxide product compared to catalysts without a recognition group.

SUBMITTER: Ulmann PA

PROVIDER: S-EPMC3930335 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction.

Ulmann Pirmin A PA Braunschweig Adam B AB Lee One-Sun OS Wiester Michael J MJ Schatz George C GC Mirkin Chad A CA

Chemical communications (Cambridge, England) 20090716 34

This study describes a heteroligated, hemilabile Pt(II)-P,S tweezer coordination complex that combines a chiral Jacobsen-Katsuki Mn(III)-salen epoxidation catalyst with an amidopyridine receptor, which leads to an inversion of the major epoxide product compared to catalysts without a recognition group. ...[more]

PMID: 20448966

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