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A diacetate ketone-catalyzed asymmetric epoxidation of olefins.

ABSTRACT: A fructose-derived diacetate ketone has been shown to be an effective catalyst for asymmetric epoxidation. High ee values have been obtained for a variety of trans and trisubstituted olefins including electron-deficient alpha,beta-unsaturated esters as well as certain cis olefins.

SUBMITTER: Wang B

PROVIDER: S-EPMC2749516 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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A diacetate ketone-catalyzed asymmetric epoxidation of olefins.

Wang Bin B Wu Xin-Yan XY Wong O Andrea OA Nettles Brian B Zhao Mei-Xin MX Chen Dajun D Shi Yian Y

The Journal of organic chemistry 20090501 10

A fructose-derived diacetate ketone has been shown to be an effective catalyst for asymmetric epoxidation. High ee values have been obtained for a variety of trans and trisubstituted olefins including electron-deficient alpha,beta-unsaturated esters as well as certain cis olefins. ...[more]

PMID: 19388627

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