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Redox-neutral ?-arylation of amines.


ABSTRACT: The direct ?-arylation/N-alkylation of cyclic amines was achieved in a redox-neutral fashion under mild conditions. Transformations occur in the absence of any additives or are promoted by simple carboxylic acids.

SUBMITTER: Chen W 

PROVIDER: S-EPMC3946350 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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Redox-neutral α-arylation of amines.

Chen Weijie W   Wilde Richard G RG   Seidel Daniel D  

Organic letters 20131213 3


The direct α-arylation/N-alkylation of cyclic amines was achieved in a redox-neutral fashion under mild conditions. Transformations occur in the absence of any additives or are promoted by simple carboxylic acids. ...[more]

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