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Excited state properties of a short ?-electron conjugated peridinin analogue.


ABSTRACT: C29-peridinin is a synthetic analogue of the important, naturally-occurring carotenoid, peridinin, found in several marine algal species. C29-peridinin has five conjugated carbon-carbon double bonds compared to eight possessed by peridinin and also lacks the methyl group functionalities typically present along the polyene chain of carotenoids. These structural modifications lead to unique excited state properties and important insights regarding the factors controlling the photophysics of peridinin and other carbonyl-containing carotenoids, which are critical components of the light-harvesting systems of many photosynthetic organisms.

SUBMITTER: Magdaong NM 

PROVIDER: S-EPMC3963168 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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Excited state properties of a short π-electron conjugated peridinin analogue.

Magdaong Nikki M NM   Niedzwiedzki Dariusz M DM   Greco Jordan A JA   Liu Hongbin H   Yano Koki K   Kajikawa Takayuki T   Sakaguchi Kazuhiko K   Katsumura Shigeo S   Birge Robert R RR   Frank Harry A HA  

Chemical physics letters 20140201


C<sub>29</sub>-peridinin is a synthetic analogue of the important, naturally-occurring carotenoid, peridinin, found in several marine algal species. C<sub>29</sub>-peridinin has five conjugated carbon-carbon double bonds compared to eight possessed by peridinin and also lacks the methyl group functionalities typically present along the polyene chain of carotenoids. These structural modifications lead to unique excited state properties and important insights regarding the factors controlling the  ...[more]

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