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Diels-Alder construction of regiodifferentiated meta-amino phenols and derivatives.


ABSTRACT: Synthetic access to regiodifferentiated meta-amino phenols is described. The strategy relies upon distinct deprotonation conditions to afford regioisomeric thermodynamic and kinetic dienes that undergo a tandem Diels-Alder and retro-Diels-Alder sequence with assorted acetylenic dienophiles to afford a range of aromatic products.

SUBMITTER: Weaver MG 

PROVIDER: S-EPMC3993616 | biostudies-literature |

REPOSITORIES: biostudies-literature

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