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Continuous flow of nitroso Diels-Alder reaction.


ABSTRACT: Our flow reaction systems have provided quantitative yields of nitroso Diels-Alder products with no byproducts in cases of cyclic dienes without temperature and pressure controls. Additionally, the reaction times were significantly shortened by using homogeneous catalyst (CuCl) or heterogeneous reagent (MnO2) in comparison with batch reaction.

SUBMITTER: Nakashima E 

PROVIDER: S-EPMC4506248 | biostudies-other | 2015 Aug

REPOSITORIES: biostudies-other

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Continuous flow of nitroso Diels-Alder reaction.

Nakashima Erika E   Yamamoto Hisashi H  

Chemical communications (Cambridge, England) 20150801 61


Our flow reaction systems have provided quantitative yields of nitroso Diels-Alder products with no byproducts in cases of cyclic dienes without temperature and pressure controls. Additionally, the reaction times were significantly shortened by using homogeneous catalyst (CuCl) or heterogeneous reagent (MnO2) in comparison with batch reaction. ...[more]

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