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ABSTRACT:
SUBMITTER: Pavlik JW
PROVIDER: S-EPMC3993889 | biostudies-literature | 2014 Mar
REPOSITORIES: biostudies-literature
Pavlik Jeffrey W JW Peng Qian Q Silvernail Nathan J NJ Alp E Ercan EE Hu Michael Y MY Zhao Jiyong J Sage J Timothy JT Scheidt W Robert WR
Inorganic chemistry 20140214 5
The vibrational spectra of two five-coordinate nitrosyl iron porphyrinates, [Fe(OEP)(NO)] (OEP = dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin) and [Fe(DPIX)(NO)] (DPIX = deuteroporphyrin IX), have been studied by oriented single-crystal nuclear resonance vibrational spectroscopy. Single crystals (both are in the triclinic crystal system) were oriented to give vibrational spectra perpendicular to the porphyrin plane. Additionally, two orthogonal in-plane measurements that were also either pe ...[more]