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?-Cyanido-?(2) C:N-dicyanido-?(2) C-bis-(N-ethyl-ethylenedi-amine-?(2) N,N')copper(II)copper(I).

ABSTRACT: In the title complex, [Cu(I)Cu(II)(CN)3(C4H12N2)2], the Cu(I) and Cu(II) ions and a bridging cyanide group lie on a twofold rotation axis. The Cu(II) ion is in a slightly-distorted square-pyramidal coordination environment, with the N atoms of the two symmetry-related N-ethyl-ethylenedi-amine ligands occupying the basal positions and an N-bonded cyanide group in the apical position. The Cu(I) ion is in a trigonal-planar coordination environment, bonded to the C atom of the bridging cyanide group and to two terminal cyanide groups. In the crystal, N-H?N hydrogen bonds involving two of the symmetry-unique N-H groups of the N-ethyl-ethylenedi-amine ligands and the N atoms of the terminal cyanide ligands link the mol-ecules into strands along [010].

SUBMITTER: Corfield PW

PROVIDER: S-EPMC3998273 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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μ-Cyanido-κ(2) C:N-dicyanido-κ(2) C-bis-(N-ethyl-ethylenedi-amine-κ(2) N,N')copper(II)copper(I).

Corfield Peter W R PW Michalski Joseph F JF

Acta crystallographica. Section E, Structure reports online 20140131 Pt 2

In the title complex, [Cu(I)Cu(II)(CN)3(C4H12N2)2], the Cu(I) and Cu(II) ions and a bridging cyanide group lie on a twofold rotation axis. The Cu(II) ion is in a slightly-distorted square-pyramidal coordination environment, with the N atoms of the two symmetry-related N-ethyl-ethylenedi-amine ligands occupying the basal positions and an N-bonded cyanide group in the apical position. The Cu(I) ion is in a trigonal-planar coordination environment, bonded to the C atom of the bridging cyanide group ...[more]

PMID: 24764834

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