Ontology highlight
ABSTRACT:
SUBMITTER: Corfield PW
PROVIDER: S-EPMC3998273 | biostudies-literature | 2014 Feb
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20140131 Pt 2
In the title complex, [Cu(I)Cu(II)(CN)3(C4H12N2)2], the Cu(I) and Cu(II) ions and a bridging cyanide group lie on a twofold rotation axis. The Cu(II) ion is in a slightly-distorted square-pyramidal coordination environment, with the N atoms of the two symmetry-related N-ethyl-ethylenedi-amine ligands occupying the basal positions and an N-bonded cyanide group in the apical position. The Cu(I) ion is in a trigonal-planar coordination environment, bonded to the C atom of the bridging cyanide group ...[more]