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1-(6-Chloro-1-methyl-1H-imidazo[4,5-c]pyridin-4-yl)-3-(2-chloro-phen-yl)urea.

ABSTRACT: In the title compound, C14H11Cl2N5O, the plane of the 1H-imidazo[4,5-c]pyridine ring system [r.m.s. deviation = 0.087?(19)?Å] makes a dihedral angle of 4.87?(10)° with the terminal phenyl ring. An intra-molecular N-H?N hydrogen bond stabilizes the mol-ecular conformation. In the crystal, N-H?O hydrogen bonds link the mol-ecules into inversion dimers. These dimers are connected by ?-? inter-actions between imidazole rings [shortest centroid-centroid distance = 3.4443?(14)?Å].

SUBMITTER: Devaru VB

PROVIDER: S-EPMC3998316 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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1-(6-Chloro-1-methyl-1H-imidazo[4,5-c]pyridin-4-yl)-3-(2-chloro-phen-yl)urea.

Devaru Venkatesh B VB Vinduvahini M M Madaiah M M Revanasiddappa H D HD Devarajegowda H C HC

Acta crystallographica. Section E, Structure reports online 20140118 Pt 2

In the title compound, C14H11Cl2N5O, the plane of the 1H-imidazo[4,5-c]pyridine ring system [r.m.s. deviation = 0.087 (19) Å] makes a dihedral angle of 4.87 (10)° with the terminal phenyl ring. An intra-molecular N-H⋯N hydrogen bond stabilizes the mol-ecular conformation. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into inversion dimers. These dimers are connected by π-π inter-actions between imidazole rings [shortest centroid-centroid distance = 3.4443 (14) Å]. ...[more]

PMID: 24764877

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