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(±)-trans-6,6'-Dieth-oxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenol monohydrate.

ABSTRACT: In the title hydrate, C24H30N2O4·H2O, the organic mol-ecule adopts an E conformation with respect to the azomethine double bonds. The cyclo-hexane ring is in a chair conformation. The dihedral angle between benzene rings is 79.6?(2)°. Two intra-molecular O-H?N hydrogen bonds are present. In the crystal, the components are linked by O-H?O hydrogen bonds and weak C-H?? inter-actions, generating a three-dimensional supramolecular architecture.

SUBMITTER: Mohan N

PROVIDER: S-EPMC3998335 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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(±)-trans-6,6'-Dieth-oxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenol monohydrate.

Mohan Nithya N Sreejith S S SS Sithambaresan M M Kurup M R Prathapachandra MR

Acta crystallographica. Section E, Structure reports online 20140122 Pt 2

In the title hydrate, C24H30N2O4·H2O, the organic mol-ecule adopts an E conformation with respect to the azomethine double bonds. The cyclo-hexane ring is in a chair conformation. The dihedral angle between benzene rings is 79.6 (2)°. Two intra-molecular O-H⋯N hydrogen bonds are present. In the crystal, the components are linked by O-H⋯O hydrogen bonds and weak C-H⋯π inter-actions, generating a three-dimensional supramolecular architecture. ...[more]

PMID: 24764896

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