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Tetra-kis(2,3,5,5-tetra-methyl-hexen-2-yl)silane.

ABSTRACT: In the title compound, C40H76Si, the Si atom is located on a special position of site symmetry -4. Thus, there is just a quarter of a mol-ecule in the asymmetric unit. The C=C double bonds exhibit a trans configuration. The Si atom and the tert-butyl group are located on the same side of the plane formed by the C=C double bond and its four substituents. The crystal packing shows no short contacts between the mol-ecules and despite the low crystal density (0.980 Mg?m(-3)), there are no significant voids in the structure.

SUBMITTER: Meyer-Wegner F

PROVIDER: S-EPMC3998395 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

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Tetra-kis(2,3,5,5-tetra-methyl-hexen-2-yl)silane.

Meyer-Wegner Frank F Bolte Michael M Lerner Hans-Wolfram HW

Acta crystallographica. Section E, Structure reports online 20140228 Pt 3

In the title compound, C40H76Si, the Si atom is located on a special position of site symmetry -4. Thus, there is just a quarter of a mol-ecule in the asymmetric unit. The C=C double bonds exhibit a trans configuration. The Si atom and the tert-butyl group are located on the same side of the plane formed by the C=C double bond and its four substituents. The crystal packing shows no short contacts between the mol-ecules and despite the low crystal density (0.980 Mg m(-3)), there are no significan ...[more]

PMID: 24765057

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