Unknown

Dataset Information

0

2-(4-Fluoro-2-nitro-phen-yl)-4-hy-droxy-9-phenyl-sulfonyl-9H-carbazole-3-carbaldehyde.


ABSTRACT: In the title compound, C25H15FN2O6S, the carbazole ring system is essentially planar, with a maximum deviation of 0.1534?(16)?Å for the C atom connected to the 4-fluoro-2-nitro-phenyl ring. It is almost orthogonal to the phenyl-sulfonyl and nitro-phenyl rings, making dihedral angles of 88.45?(8) and 79.26?(7)°, respectively. The mol-ecular structure is stabilized by O-H?O and C-H?O hydrogen bonds, which generate three S(6) ring motifs. In the crystal, mol-ecules are linked by two C-H?O hydrogen bonds, which generate C(6) and C(9) chains running in the [100] and [010] directions, respectively, so forming a two-dimensional network lying parallel to (001). There are also supra-molecular R 4 (3)(28) graph-set ring motifs enclosed within these networks.

SUBMITTER: Gopinath S 

PROVIDER: S-EPMC3998398 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

altmetric image

Publications

2-(4-Fluoro-2-nitro-phen-yl)-4-hy-droxy-9-phenyl-sulfonyl-9H-carbazole-3-carbaldehyde.

Gopinath S S   Sethusankar K K   Saravanan Velu V   Mohanakrishnan Arasambattu K AK  

Acta crystallographica. Section E, Structure reports online 20140212 Pt 3


In the title compound, C25H15FN2O6S, the carbazole ring system is essentially planar, with a maximum deviation of 0.1534 (16) Å for the C atom connected to the 4-fluoro-2-nitro-phenyl ring. It is almost orthogonal to the phenyl-sulfonyl and nitro-phenyl rings, making dihedral angles of 88.45 (8) and 79.26 (7)°, respectively. The mol-ecular structure is stabilized by O-H⋯O and C-H⋯O hydrogen bonds, which generate three S(6) ring motifs. In the crystal, mol-ecules are linked by two C-H⋯O hydrogen  ...[more]

Similar Datasets

| S-EPMC3884462 | biostudies-literature
| S-EPMC3998368 | biostudies-literature
| S-EPMC3998565 | biostudies-literature
| S-EPMC3007870 | biostudies-literature
| S-EPMC4050995 | biostudies-literature
| S-EPMC4257421 | biostudies-literature
| S-EPMC3998409 | biostudies-literature
| S-EPMC5137599 | biostudies-literature
| S-EPMC3201353 | biostudies-literature
| S-EPMC4647343 | biostudies-literature