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2-(4,5-Dimeth-oxy-2-nitro-phen-yl)-4-meth-oxy-9-phenyl-sulfonyl-9H-carbazole-3-carbaldehyde.


ABSTRACT: In the title compound, C28H22N2O8S, the carbazole ring system is roughly planar, with a maximum deviation of 0.084?(3)?Å for the C atom connected to the 4,5-dimeth-oxy-2-nitro-phenyl ring. The dihedral angle between the carbazole system and the dimeth-oxy-substituted nitro-phenyl ring is 57.05?(10)°. The aldehyde C atom deviates by 0.164?(5)?Å from its attached carbazole ring system. The mol-ecular structure is stabilized by C-H?O inter-actions which generate two S(6) and one S(7) ring motif. In the crystal, mol-ecules are linked by C-H?O hydrogen bonds, forming R 3 (3)(15) ring motifs, which are further crosslinked by R 3 (2)(19) ring motifs, resulting in (002) layers. The crystal packing also features C-H?? inter-actions.

SUBMITTER: Narayanan P 

PROVIDER: S-EPMC3998565 | biostudies-literature | 2014 Apr

REPOSITORIES: biostudies-literature

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2-(4,5-Dimeth-oxy-2-nitro-phen-yl)-4-meth-oxy-9-phenyl-sulfonyl-9H-carbazole-3-carbaldehyde.

Narayanan P P   Sethusankar K K   Saravanan Velu V   Mohanakrishnan Arasambattu K AK  

Acta crystallographica. Section E, Structure reports online 20140312 Pt 4


In the title compound, C28H22N2O8S, the carbazole ring system is roughly planar, with a maximum deviation of 0.084 (3) Å for the C atom connected to the 4,5-dimeth-oxy-2-nitro-phenyl ring. The dihedral angle between the carbazole system and the dimeth-oxy-substituted nitro-phenyl ring is 57.05 (10)°. The aldehyde C atom deviates by 0.164 (5) Å from its attached carbazole ring system. The mol-ecular structure is stabilized by C-H⋯O inter-actions which generate two S(6) and one S(7) ring motif. In  ...[more]

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