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Tetra-kis(2-amino-5-chloro-pyridinium) di-hydrogen cyclo-hexa-phosphate.

ABSTRACT: In the crystal structure of the title compound, 4C5H6ClN2 (+)·H2P6O18 (4-), the [H2P6O18](4-) anions are interconnected by O-H?O hydrogen bonds, leading to the formation of infinite ribbons extending along the a-axis direction. These ribbons are linked to the organic cations, via N-H?O and C-H?O hydrogen bonds, into a three-dimensional network. The six P atoms of the [H2P6O18](4-) anion form a chair conformation. The complete cyclohexaphosphate anion is generated by inversion symmetry.

SUBMITTER: Hamdi A

PROVIDER: S-EPMC3998406 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

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Tetra-kis(2-amino-5-chloro-pyridinium) di-hydrogen cyclo-hexa-phosphate.

Hamdi Ahmed A Khederi Lamia L Rzaigui Mohamed M

Acta crystallographica. Section E, Structure reports online 20140222 Pt 3

In the crystal structure of the title compound, 4C5H6ClN2 (+)·H2P6O18 (4-), the [H2P6O18](4-) anions are interconnected by O-H⋯O hydrogen bonds, leading to the formation of infinite ribbons extending along the a-axis direction. These ribbons are linked to the organic cations, via N-H⋯O and C-H⋯O hydrogen bonds, into a three-dimensional network. The six P atoms of the [H2P6O18](4-) anion form a chair conformation. The complete cyclohexaphosphate anion is generated by inversion symmetry. ...[more]

PMID: 24765034

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