Browse
Submit Data
Databases
API
Help

Dataset Information

31 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Cyclo-hexyl-ammonium nitrate.

ABSTRACT: In the title salt, C6H14N(+)·NO3 (-), the cyclo-hexyl ring adopts a chair conformation. The ammonium group occupies an equatorial position and the crystal struture is stabilized by inter-molecular N-H?O hydrogen-bonding inter-actions, resulting in a three-dimensional network.

SUBMITTER: Bagabas AA

PROVIDER: S-EPMC3998418 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Cyclo-hexyl-ammonium nitrate.

Bagabas Abdulaziz A AA Aboud Mohamed F A MF Shemsi Ahsan M AM Addurihem Emad S ES Al-Othman Zeid A ZA Chidan Kumar C S CS Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20140205 Pt 3

In the title salt, C6H14N(+)·NO3 (-), the cyclo-hexyl ring adopts a chair conformation. The ammonium group occupies an equatorial position and the crystal struture is stabilized by inter-molecular N-H⋯O hydrogen-bonding inter-actions, resulting in a three-dimensional network. ...[more]

PMID: 24764971

Similar Datasets

Crystal structure of di-cyclo-hexyl-ammonium nitrate(V).

Project description:In the title mol-ecular salt, C12H24N(+)·NO3 (-), the cyclohexyl rings adopt chair conformations with the exocyclic C-N bonds in equatorial orientations. In the crystal, a bifurcated N-H?(O,O) hydrogen bond links the cation to the anion; the ion pairs are linked via C-H?O hydrogen bonds, forming layers in the ac plane.

| S-EPMC4645052 | biostudies-literature

Bis(cyclo-hexyl-ammonium) terephthalate.

Project description:In the title mol-ecular salt, 2C(6)H(11)NH(3) (+)·C(8)H(4)O(4) (2-), the terephthalate dianion is close to being planar (r.m.s. deviation = 0.049 Å). In the crystal, the cations and anions are linked by N-H⋯O hydrogen bonds into (010) sheets. Of the four terephthalate O atoms, two accept two hydrogen bonds each and two accept one hydrogen bond each.

| S-EPMC3344674 | biostudies-literature

Cyclo-hexyl-ammonium 4-meth-oxy-benzoate.

Project description:In the crystal of the title molecular salt, C(6)H(14)N(+)·C(8)H(7)O(3) (-), strong N-H?O hydrogen bonds are formed between the ammonium H atoms and the carboxyl-ate O atoms. The resulting supra-molecular structure is based on chains running in the [010] direction. The dihedral angle between the -CO(2) group and the benzene ring is 8.94?(17)° and the methoxy C atom deviates by 1.374?Å from the ring.

| S-EPMC3213617 | biostudies-literature

Bis(di-cyclo-hexyl-ammonium) sulfate dihydrate.

Project description:In the title dihydrate salt, 2C12H24N(+)·SO4 (2-)·2H2O, the cation possesses twofold rotational symmetry, with the N atom situated on the twofold axis. The sulfate anion has fourfold roto-inversion symmetry, with the S atom located on the -4 axis. In the crystal, the components are linked via ammonium-sulfate N-H⋯O and water-sulfate O-H⋯O hydrogen bonds, forming a three-dimensional network.

| S-EPMC3998410 | biostudies-literature

Crystal structure of cyclo-hexyl-ammonium thio-cyanate.

Project description:In the title salt, C6H11NH3 (+)·SCN(-), the cyclo-hexyl-ammonium ring adopts a slightly distorted chair conformation. The ammonium group occupies an equatorial position to minimize 1,3 and 1,5 diaxial inter-actions. In the crystal, the components are linked by N-H⋯N and N-H⋯S hydrogen-bonding inter-actions, resulting in a three-dimensional network.

| S-EPMC4331923 | biostudies-literature

Dicyclo-hexyl-ammonium bis-(chloro-difluoro-acetato-κO)cyclo-hexyl-diphenyl-stannate(IV).

Project description:In the title mixed-organyl stannate, (C(12)H(24)N)[Sn(C(6)H(5))(2)(C(6)H(11))(CClF(2)O(2))(2)], there are two cations and two anions in the asymmetric unit. Each five-coordinate Sn atom shows trans-C(3)SnO(2) trigonal bipyramidal coordination. The four Sn-O distances are approximately equal in the two independent anions. Each ammonium cation serves as a hydrogen-bond donor to two stannates, the hydrogen-bonding inter-actions giving rise to linear hydrogen-bonded chains.

| S-EPMC2961113 | biostudies-literature

Bis(cyclo-hexyl-ammonium) tetra-chlorido-diphenyl-stannate(IV).

Project description:The title compound, (C6H14N)2[Sn(C6H5)2Cl4], contains cyclo-hexyl-ammonium cations in general positions and a stannate(IV) anion that is located on a twofold rotation axis. The Sn(IV) atom in the complex anion is surrounded by four Cl(-) ligands and two trans-phenyl groups in a distorted octa-hedral configuration. The anions are connected with the cations through N-H?Cl hydrogen bonds. Every cation is involved in three N-H?Cl bonds to the chloride ligands of three different anions, and each chloride ligand is linked to two cations. This arrangement leads to a layered structure parallel to (010).

| S-EPMC4051057 | biostudies-literature

Bis(cyclo-hexyl-ammonium) tetra-chlorido-(oxalato)stannate(IV).

Project description:The title salt, (C6H14N)2[Sn(C2O4)Cl4], was obtained as a by-product from the reaction between 2C6H14N(+)·C2O4 (2-)·1.5H2O and SnCl2·2H2O. The cyclo-hexyl-ammonium cation has a chair conformation. The complex anion consists of an oxalate anion chelating the SnCl4 moiety, resulting in a distorted octa-hedral coordination sphere of the Sn(IV) atom with the O atoms in equatorial cis positions. In the crystal, cations and anions are linked through N-H⋯O and N-H⋯Cl inter-actions into a layered arrangement parallel to (100).

| S-EPMC3793702 | biostudies-literature

Cyclo-hexyl-ammonium acetate-N,N',N''-tricyclo-hexyl-phospho-ric triamide (1/1).

Project description:In the phospho-ric triamide mol-ecule of the title compound, C(6)H(14)N(+)·C(2)H(3)O(2) (-)·C(18)H(36)N(3)OP, the P atom displays a distorted tetra-hedral geometry and the cyclo-hexyl rings adopt chair conformations with the NH groups in equatorial positions. In the crystal, the cations, anions and phosphoric triamide mol-ecules are linked via N-H⋯O hydrogen bonds into a two-dimensional array parallel to the bc plane. The O atom of the P(O) group acts as a double-hydrogen-bond acceptor.

| S-EPMC3394049 | biostudies-literature

Crystal structure of bis-(cyclo-hexyl-ammonium) di-phenyl-dioxalatostannate(IV).

Project description:Reaction of oxalic acid and di-phenyl-tin dichloride in the presence of cyclo-hexyl-amine led to the formation of the title salt, (C6H14N)2[Sn(C6H5)2(C2O4)2]. The dianion is made up from an Sn(C6H5)2 moiety cis-coordinated by two chelating oxalate anions, leading to an overall distorted octa-hedral coordination geometry of the Sn(IV) atom. The negative charges are compensated by two surrounding cyclo-hexyl-ammonium cations adopting chair conformations each. In the crystal, anions and cations are linked via a network of N-H?O hydrogen bonds into a layered arrangement parallel to (101).

| S-EPMC4384614 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data