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4-Hy-droxy-3-meth-oxy-benzaldehyde 4-phenyl-thio-semicarbazone.

ABSTRACT: In the title compound, C15H15N3O2S, the central C-N-N-C unit has an anti conformation [torsion angle = -170.17?(15)°]. The phenyl substituent is oriented perpendicular to this unit [dihedral angle of 89.2?(1)°], whereas the substituted ring is rotated out of this plane by only 18.86?(17)°. In the crystal, mol-ecules are linked by pairs of N-H?S hydrogen bonds into inversion dimers that are further connected via N-H?O and O-H?S hydrogen bonds into a three-dimensional network.

SUBMITTER: de Oliveira AB

PROVIDER: S-EPMC3998432 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

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4-Hy-droxy-3-meth-oxy-benzaldehyde 4-phenyl-thio-semicarbazone.

de Oliveira Adriano Bof AB Feitosa Bárbara Regina Santos BR Näther Christian C Jess Inke I

Acta crystallographica. Section E, Structure reports online 20140212 Pt 3

In the title compound, C15H15N3O2S, the central C-N-N-C unit has an anti conformation [torsion angle = -170.17 (15)°]. The phenyl substituent is oriented perpendicular to this unit [dihedral angle of 89.2 (1)°], whereas the substituted ring is rotated out of this plane by only 18.86 (17)°. In the crystal, mol-ecules are linked by pairs of N-H⋯S hydrogen bonds into inversion dimers that are further connected via N-H⋯O and O-H⋯S hydrogen bonds into a three-dimensional network. ...[more]

PMID: 24764990

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