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Bis(4-hy-droxy-3-meth-oxy-benzaldehyde 4-phenyl-thio-semicarbazonato-N (1),S)nickel(II).

ABSTRACT: In the title compound, [Ni(C15H14N3O2S)2], the Ni(II) atom lies on a center of symmetry. The deprotonated ligands act as N,S-donors, forming five-membered metalla-rings. The Ni(II) atom is four-coordinated in a slightly distorted square-planar environment. In the crystal, the discrete complex mol-ecules are linked by weak N-H?O hydrogen bonds, generating chains along [110]. The chains are further connected via weak O-H?N inter-actions into a layered network extending parallel to (001).

SUBMITTER: de Oliveira AB

PROVIDER: S-EPMC4011249 | biostudies-literature | 2014 May

REPOSITORIES: biostudies-literature

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Bis(4-hy-droxy-3-meth-oxy-benzaldehyde 4-phenyl-thio-semicarbazonato-N (1),S)nickel(II).

de Oliveira Adriano Bof AB Feitosa Bárbara Regina Santos BR Näther Christian C Jess Inke I

Acta crystallographica. Section E, Structure reports online 20140430 Pt 5

In the title compound, [Ni(C15H14N3O2S)2], the Ni(II) atom lies on a center of symmetry. The deprotonated ligands act as N,S-donors, forming five-membered metalla-rings. The Ni(II) atom is four-coordinated in a slightly distorted square-planar environment. In the crystal, the discrete complex mol-ecules are linked by weak N-H⋯O hydrogen bonds, generating chains along [110]. The chains are further connected via weak O-H⋯N inter-actions into a layered network extending parallel to (001). ...[more]

PMID: 24860322

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