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{N,N'-Bis-[2-(di-phenyl-phosphan-yl)ethan-1-yl-idene]ethyl-enedi-amine}bromido-(p-toluene-sulfonyl-methyl isocyanide)iron(II) tetra-phenyl-borate.

ABSTRACT: In the title compound, [FeBr(C9H9NO2S)(C30H30N2P2)][B(C6H5)4], the Fe(II) ion is in a distorted octa-hedral CBrN2P2 coordination geometry with a P-Fe-P angle of 109.95?(3)°. The relative orientation of the p-toluene-sulfonyl-methyl isocyanide ligand is defined by the C-S-C-N torsion angle of 67.1?(2)°. In the crystal, pairs of weak C-H?O hydrogen bonds connect the cations into inversion dimers, forming R 2 (2)(8) rings.

SUBMITTER: Sues PE

PROVIDER: S-EPMC3998587 | biostudies-literature | 2014 Apr

REPOSITORIES: biostudies-literature

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{N,N'-Bis-[2-(di-phenyl-phosphan-yl)ethan-1-yl-idene]ethyl-enedi-amine}bromido-(p-toluene-sulfonyl-methyl isocyanide)iron(II) tetra-phenyl-borate.

Sues Peter E PE Lough Alan J AJ Morris Robert H RH

Acta crystallographica. Section E, Structure reports online 20140326 Pt 4

In the title compound, [FeBr(C9H9NO2S)(C30H30N2P2)][B(C6H5)4], the Fe(II) ion is in a distorted octa-hedral CBrN2P2 coordination geometry with a P-Fe-P angle of 109.95 (3)°. The relative orientation of the p-toluene-sulfonyl-methyl isocyanide ligand is defined by the C-S-C-N torsion angle of 67.1 (2)°. In the crystal, pairs of weak C-H⋯O hydrogen bonds connect the cations into inversion dimers, forming R 2 (2)(8) rings. ...[more]

PMID: 24826104

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