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Bis(2,6-dimethyl-phenyl isocyanide-κC)gold(I) tetra-fluorido-borate.

ABSTRACT: In the title compound, [Au(C(9)H(9)N)(2)]BF(4), the Au(I) cation adopts an almost linear AuC(2) geometry. The cation is bowed due to crystal packing effects, and the dihedral angle between the xylyl rings is 52.3 (7)°.

SUBMITTER: Singa TP

PROVIDER: S-EPMC2959487 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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Bis(2,6-dimethyl-phenyl isocyanide-κC)gold(I) tetra-fluorido-borate.

Singa Timi P TP Dipasquale Antonio G AG Rheingold Arnold L AL Kubiak Clifford P CP

Acta crystallographica. Section E, Structure reports online 20080906 Pt 10

In the title compound, [Au(C(9)H(9)N)(2)]BF(4), the Au(I) cation adopts an almost linear AuC(2) geometry. The cation is bowed due to crystal packing effects, and the dihedral angle between the xylyl rings is 52.3 (7)°. ...[more]

PMID: 21200982

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